Notices
The Basement Non-Honda/Acura discussion. Content should be tasteful and "primetime" safe.

if 2 atoms fulfill the same quantum number...

Thread Tools
 
Old 11-09-2004, 06:34 PM
  #1  
redgoober4life
I eat plastic.
Thread Starter
 
redgoober4life's Avatar
 
Join Date: Dec 2002
Location: Detroit, MI
Posts: 15,177
Likes: 0
Received 0 Likes on 0 Posts
Default if 2 atoms fulfill the same quantum number...

Ca vs. Sc

4s^2 vs. 4s^2 3d^1

20 electrons vs. 21 electrons

20 protons vs. 21 protons

Which would be bigger in size?
Old 11-09-2004, 06:37 PM
  #2  
strychnine
i am legend
 
strychnine's Avatar
 
Join Date: Jul 2003
Location: northwest NC
Posts: 3,104
Likes: 0
Received 0 Likes on 0 Posts
Default

quantum leap was a good show, if that guy knew wtf youre talking about he probably could have gone home sooner.
Old 11-09-2004, 06:42 PM
  #3  
LT
The deer had to die!
 
LT's Avatar
 
Join Date: Jun 2002
Location: Fussa, Japan
Posts: 39,835
Likes: 0
Received 0 Likes on 0 Posts
Default

Sc - has another energy level
Old 11-09-2004, 06:42 PM
  #4  
98CoupeV6
lots and lots of fail
 
98CoupeV6's Avatar
 
Join Date: Dec 1999
Location: Deeeeeeeeeeeeeeetroit
Posts: 23,004
Likes: 0
Received 1 Like on 1 Post
Default

Depends on their position on the table fool...

atoms decrease in size left to right and down to up.
Old 11-09-2004, 06:45 PM
  #5  
dubcac
I
 
dubcac's Avatar
 
Join Date: Jan 2001
Location: Westside til I die
Posts: 56,525
Likes: 0
Received 0 Likes on 0 Posts
Default

Originally Posted by LT69Padawan6
Sc - has another energy level
:ts:

Correct, he is.
Old 11-09-2004, 06:49 PM
  #6  
redgoober4life
I eat plastic.
Thread Starter
 
redgoober4life's Avatar
 
Join Date: Dec 2002
Location: Detroit, MI
Posts: 15,177
Likes: 0
Received 0 Likes on 0 Posts
Default

Originally Posted by LT69Padawan6
Sc - has another energy level
but if it were Sc (1+), Ca would be larger?

Also this really doesn't apply to the assignment since most of them are ions...but...if size decreases in a period as you go across from left to right, wouldn't this prove that wrong? (in the case of the non-charged in the previous question) I'm confused
Old 11-09-2004, 06:57 PM
  #7  
redgoober4life
I eat plastic.
Thread Starter
 
redgoober4life's Avatar
 
Join Date: Dec 2002
Location: Detroit, MI
Posts: 15,177
Likes: 0
Received 0 Likes on 0 Posts
Default

What is also more confusing to this is that even though Sc does have one electron in the 3d subshell, it has one more proton. More protons=more internal pull on the electrons which would decrease the size. So I don't know if having more electrons would necessarily make it larger overall. I don't know though
Old 11-09-2004, 07:03 PM
  #8  
Kestrel
Push to shock!
 
Kestrel's Avatar
 
Join Date: Sep 2002
Location: Palo Alto, CA
Posts: 4,583
Likes: 0
Received 0 Likes on 0 Posts
Default

Originally Posted by redgoober4life
but if it were Sc (1+), Ca would be larger?
Correct. The outer electron is lost, and there are now 21 protons to attract 20 electrons, so it pulls them in closer.
Old 11-09-2004, 07:05 PM
  #9  
Kestrel
Push to shock!
 
Kestrel's Avatar
 
Join Date: Sep 2002
Location: Palo Alto, CA
Posts: 4,583
Likes: 0
Received 0 Likes on 0 Posts
Default

Originally Posted by redgoober4life
What is also more confusing to this is that even though Sc does have one electron in the 3d subshell, it has one more proton. More protons=more internal pull on the electrons which would decrease the size. So I don't know if having more electrons would necessarily make it larger overall. I don't know though
If the 3s level is full, the electrons tend to "shield" the protons from the electrons in the next higher energy level shell, so the protons have less pull on the electrons in the 3d level.
Old 11-09-2004, 07:05 PM
  #10  
redgoober4life
I eat plastic.
Thread Starter
 
redgoober4life's Avatar
 
Join Date: Dec 2002
Location: Detroit, MI
Posts: 15,177
Likes: 0
Received 0 Likes on 0 Posts
Default

Originally Posted by Kestrel
Correct. The outer electron is lost, and there are now 21 protons to attract 20 electrons, so it pulls them in closer.
But I'm having difficulty with Ca < Sc in the non-ion. Even though Sc has more elections and occupies another subshell, the atomic radius anywhere I can find looks to be smaller. Is this because it has another proton, and therefor, more pull?



All times are GMT -8. The time now is 08:21 AM.