i used engine block enamel, available from autobarn
its rated to 1200* peak and it is ceramic based.
they also have high temp clearcoat
ive used it with no issues on calipers, tranny covers, oil pan, engine block
just be careful with brake cleaner around the painted calipers.
brake cleaner will take the paint off no problem, even if the paint has been baked on.
~kris